DNA molecular solvation in neat ionic liquids.
نویسندگان
چکیده
The structural and molecular mechanism of double-stranded DNA (dsDNA) and single-stranded DNA (ssDNA) solvation in ten room-temperature ionic liquids (RTILs) is disclosed herein. We show that the Drew Dickerson B DNA structure solvated in neat RTILs based on imidazolium, oxazolium, pyrrolidinium, pyrimidinium and quaternary ammonium cations, combined with hexafluorophosphate and tetrafluorobromide anions (Figure 1), is able to maintain the native dsDNA B form confor-
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ورودعنوان ژورنال:
- Chemphyschem : a European journal of chemical physics and physical chemistry
دوره 12 2 شماره
صفحات -
تاریخ انتشار 2011